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PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE
SUGIMURA, A; IWAMOTO, M; ZHONGCAN, OY; SUGIMURA, A , OSAKA SANGYO UNIV,DEPT INFORMAT SYST ENGN,DAITO,OSAKA 574,JAPAN.
1994
发表期刊PHYSICAL REVIEW E
ISSN1063-651X
卷号50期号:1页码:614-617
摘要On the basis of the interaction of dipolar molecules with a liquid surface we calculate the thermodynamics of the molecular orientation and related mechanical and electric effects for a monolayer of molecules on an air-liquid interface. It is shown that compressing the molecular area should lead to a weak first order phase transition of the molecules from isotropic to polar orientation. Although the main source of the phase transition may not be the polar interactions, the polar nature of the molecules offers a nice way of monitoring the phase transition. The anomalous slope of the pressure-area isotherms is found to be related to the transition. It was shown theoretically that a Maxwell displacement current with a sharp pulse shape is generated at the onset of the transition.
部门归属TOKYO INST TECHNOL,DEPT PHYS ELECTR,TOKYO 152,JAPAN; ACAD SINICA,INST THEORET PHYS,BEIJING 100080,PEOPLES R CHINA
关键词Water-interface Grafted Rods Monolayers Diffraction Films
学科领域Physics
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收录类别SCI
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/11880
专题理论物理所SCI论文
通讯作者SUGIMURA, A , OSAKA SANGYO UNIV,DEPT INFORMAT SYST ENGN,DAITO,OSAKA 574,JAPAN.
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SUGIMURA, A,IWAMOTO, M,ZHONGCAN, OY,et al. PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE[J]. PHYSICAL REVIEW E,1994,50(1):614-617.
APA SUGIMURA, A,IWAMOTO, M,ZHONGCAN, OY,&SUGIMURA, A , OSAKA SANGYO UNIV,DEPT INFORMAT SYST ENGN,DAITO,OSAKA 574,JAPAN..(1994).PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE.PHYSICAL REVIEW E,50(1),614-617.
MLA SUGIMURA, A,et al."PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE".PHYSICAL REVIEW E 50.1(1994):614-617.
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