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SUGIMURA, A; IWAMOTO, M; ZHONGCAN, OY; SUGIMURA, A , OSAKA SANGYO UNIV,DEPT INFORMAT SYST ENGN,DAITO,OSAKA 574,JAPAN.
PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE
Source PublicationPHYSICAL REVIEW E
KeywordWater-interface Grafted Rods Monolayers Diffraction Films
AbstractOn the basis of the interaction of dipolar molecules with a liquid surface we calculate the thermodynamics of the molecular orientation and related mechanical and electric effects for a monolayer of molecules on an air-liquid interface. It is shown that compressing the molecular area should lead to a weak first order phase transition of the molecules from isotropic to polar orientation. Although the main source of the phase transition may not be the polar interactions, the polar nature of the molecules offers a nice way of monitoring the phase transition. The anomalous slope of the pressure-area isotherms is found to be related to the transition. It was shown theoretically that a Maxwell displacement current with a sharp pulse shape is generated at the onset of the transition.
1994
ISSN1063-651X
Volume50Issue:1Pages:614-617
Subject AreaPhysics
Indexed BySCI
Document Type期刊论文
Identifierhttp://ir.itp.ac.cn/handle/311006/11880
Collection理论物理所科研产出_SCI论文
Corresponding AuthorSUGIMURA, A , OSAKA SANGYO UNIV,DEPT INFORMAT SYST ENGN,DAITO,OSAKA 574,JAPAN.
Recommended Citation
GB/T 7714
SUGIMURA, A,IWAMOTO, M,ZHONGCAN, OY,et al. PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE[J]. PHYSICAL REVIEW E,1994,50(1):614-617.
APA SUGIMURA, A,IWAMOTO, M,ZHONGCAN, OY,&SUGIMURA, A , OSAKA SANGYO UNIV,DEPT INFORMAT SYST ENGN,DAITO,OSAKA 574,JAPAN..(1994).PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE.PHYSICAL REVIEW E,50(1),614-617.
MLA SUGIMURA, A,et al."PHASE-TRANSITION OF MOLECULAR-ORIENTATION AT THE LIQUID-AIR INTERFACE".PHYSICAL REVIEW E 50.1(1994):614-617.
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