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Pattern formation and chiral phase separation by compression: Racemic monolayer viewed as Bragg-Williams binary cholesterics
Iwamoto, M; Wu, CX; Zhong-Can, OY; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 Ookayama, Tokyo 152, Japan.
1999
发表期刊PHYSICAL REVIEW E
ISSN1063-651X
卷号59期号:1页码:586-590
摘要The monolayer of racemic amphiphiles is studied as a film of cholesteric liquid crystal (ChLC), mixed by the left- and right-handed chiral enantiomers. The chiral phase separation (CPS) and molecular orientation pattern are analyzed by Bragg-Williams theory for binary mixtures and the curvature-elastic model of ChLC. It is shown that below a certain critical temperature a compression can induce transition from racemic phase to CPS phase with a stripe-pattern formation. This gives a clear explanation of CPS in a racemic monolayer recognized by Lundquist [Ark. Kemi. 17, 183 (1960)], and observed recently by Eckhardt ct al. [Nature (London) 362, 614 (1993)]. [S1063-651X(99)11301-1].
部门归属Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 152, Japan; Acad Sinica, Inst Theoret Phys, Beijing 100080, Peoples R China
关键词Liquid-crystal Films
学科领域Physics
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收录类别SCI
WOS记录号WOS:000078111900075
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被引频次:6[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/12212
专题理论物理所1978-2010年知识产出
通讯作者Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 Ookayama, Tokyo 152, Japan.
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Iwamoto, M,Wu, CX,Zhong-Can, OY,et al. Pattern formation and chiral phase separation by compression: Racemic monolayer viewed as Bragg-Williams binary cholesterics[J]. PHYSICAL REVIEW E,1999,59(1):586-590.
APA Iwamoto, M,Wu, CX,Zhong-Can, OY,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 Ookayama, Tokyo 152, Japan..(1999).Pattern formation and chiral phase separation by compression: Racemic monolayer viewed as Bragg-Williams binary cholesterics.PHYSICAL REVIEW E,59(1),586-590.
MLA Iwamoto, M,et al."Pattern formation and chiral phase separation by compression: Racemic monolayer viewed as Bragg-Williams binary cholesterics".PHYSICAL REVIEW E 59.1(1999):586-590.
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