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Wu, CX; Ou-Yang, Z; Iwamoto, M; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528852, Japan.
Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface
Source PublicationJOURNAL OF CHEMICAL PHYSICS
KeywordPhospholipid Monolayers Displacement Current Langmuir Monolayers Films Interface Behavior
AbstractWe build up a self-consistent equation and derive a general equation of orientational phase transition between a normal-director phase and a tilted-director phase for smectic monolayers on a water surface under monolayer compression with a consideration of molecular configuration. A differential dielectric constant for monolayer films is discovered and discussed. The change of the first orientational order parameter and the dielectric constant at the polar orientational phase transition point is also examined. It is found that the influence of the polar orientational phase transition on the first orientational order parameter in monolayer films is clear compared with that on the dielectric constant. This reveals that Maxwell-displacement-current measuring technique would be a useful way to measure such a phase transition. (C) 1998 American Institute of Physics.
1998
ISSN0021-9606
Volume109Issue:11Pages:4552-4561
Subject AreaPhysics
Indexed BySCI
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Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.itp.ac.cn/handle/311006/12265
Collection理论物理所科研产出_SCI论文
Corresponding AuthorIwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528852, Japan.
Recommended Citation
GB/T 7714
Wu, CX,Ou-Yang, Z,Iwamoto, M,et al. Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface[J]. JOURNAL OF CHEMICAL PHYSICS,1998,109(11):4552-4561.
APA Wu, CX,Ou-Yang, Z,Iwamoto, M,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528852, Japan..(1998).Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface.JOURNAL OF CHEMICAL PHYSICS,109(11),4552-4561.
MLA Wu, CX,et al."Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface".JOURNAL OF CHEMICAL PHYSICS 109.11(1998):4552-4561.
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