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Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface
Wu, CX; Ou-Yang, Z; Iwamoto, M; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528852, Japan.
1998
发表期刊JOURNAL OF CHEMICAL PHYSICS
ISSN0021-9606
卷号109期号:11页码:4552-4561
摘要We build up a self-consistent equation and derive a general equation of orientational phase transition between a normal-director phase and a tilted-director phase for smectic monolayers on a water surface under monolayer compression with a consideration of molecular configuration. A differential dielectric constant for monolayer films is discovered and discussed. The change of the first orientational order parameter and the dielectric constant at the polar orientational phase transition point is also examined. It is found that the influence of the polar orientational phase transition on the first orientational order parameter in monolayer films is clear compared with that on the dielectric constant. This reveals that Maxwell-displacement-current measuring technique would be a useful way to measure such a phase transition. (C) 1998 American Institute of Physics.
部门归属Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528852, Japan; Tsing Hua Univ, Ctr Adv Study, Beijing 100084, Peoples R China; Acad Sinica, Inst Theoret Phys, Beijing 100080, Peoples R China
关键词Phospholipid Monolayers Displacement Current Langmuir Monolayers Films Interface Behavior
学科领域Physics
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收录类别SCI
WOS记录号WOS:000075839100046
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被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/12265
专题理论物理所SCI论文
通讯作者Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528852, Japan.
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Wu, CX,Ou-Yang, Z,Iwamoto, M,et al. Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface[J]. JOURNAL OF CHEMICAL PHYSICS,1998,109(11):4552-4561.
APA Wu, CX,Ou-Yang, Z,Iwamoto, M,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528852, Japan..(1998).Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface.JOURNAL OF CHEMICAL PHYSICS,109(11),4552-4561.
MLA Wu, CX,et al."Polar orientational phase transition and differential dielectric constant of smectic monolayers on a water surface".JOURNAL OF CHEMICAL PHYSICS 109.11(1998):4552-4561.
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