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Iwamoto, M; Wu, CX; Zhong-can, OY; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface
发表期刊CHEMICAL PHYSICS LETTERS
关键词Maxwell Displacement Current Air Interface Simulation Dynamics Microscopy Films Model
摘要Monolayers of amphiphilic molecules at the liquid-air interface are investigated, taking into account the steric repulsion between molecules and the Coulomb attractive interaction of dipoles with the liquid surface. It is shown that the former favors a perpendicular alignment of molecules at the surface (SmA(p) phase) and the latter gives a tilted orientation (SmCp phase). As the temperature decreases, the competition between these two interactions leads to a second-order phase transition from SmA(p) to SmCp. The large pretransitional fluctuation of the tilt angle at a critical molecular area is predicted. (C) 1999 Elsevier Science B.V. All rights reserved.
1999
ISSN0009-2614
卷号312期号:1页码:7-13
学科领域Physics
收录类别SCI
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被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/13085
专题理论物理所科研产出_SCI论文
通讯作者Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
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Iwamoto, M,Wu, CX,Zhong-can, OY,et al. Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface[J]. CHEMICAL PHYSICS LETTERS,1999,312(1):7-13.
APA Iwamoto, M,Wu, CX,Zhong-can, OY,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan..(1999).Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface.CHEMICAL PHYSICS LETTERS,312(1),7-13.
MLA Iwamoto, M,et al."Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface".CHEMICAL PHYSICS LETTERS 312.1(1999):7-13.
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