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题名: Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface
作者: Iwamoto, M ;  Wu, CX ;  Zhong-can, OY
刊名: CHEMICAL PHYSICS LETTERS
出版日期: 1999
卷号: 312, 期号:1, 页码:7-13
关键词: MAXWELL DISPLACEMENT CURRENT ;  AIR INTERFACE ;  SIMULATION ;  DYNAMICS ;  MICROSCOPY ;  FILMS ;  MODEL
学科分类: Physics
通讯作者: Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
部门归属: Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan; Tsing Hua Univ, Ctr Adv Study, Beijing 100084, Peoples R China; Acad Sinica, Inst Theoret Phys, Beijing 100080, Peoples R China
英文摘要: Monolayers of amphiphilic molecules at the liquid-air interface are investigated, taking into account the steric repulsion between molecules and the Coulomb attractive interaction of dipoles with the liquid surface. It is shown that the former favors a perpendicular alignment of molecules at the surface (SmA(p) phase) and the latter gives a tilted orientation (SmCp phase). As the temperature decreases, the competition between these two interactions leads to a second-order phase transition from SmA(p) to SmCp. The large pretransitional fluctuation of the tilt angle at a critical molecular area is predicted. (C) 1999 Elsevier Science B.V. All rights reserved.
收录类别: SCI
原文出处: 查看原文
WOS记录号: WOS:000083203600002
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.itp.ac.cn/handle/311006/13085
Appears in Collections:理论物理所1978-2010年知识产出_期刊论文

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Recommended Citation:
Iwamoto, M,Wu, CX,Zhong-can, OY. Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface[J]. CHEMICAL PHYSICS LETTERS,1999,312(1):7-13.
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