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Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface
Iwamoto, M; Wu, CX; Zhong-can, OY; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
1999
发表期刊CHEMICAL PHYSICS LETTERS
ISSN0009-2614
卷号312期号:1页码:7-13
摘要Monolayers of amphiphilic molecules at the liquid-air interface are investigated, taking into account the steric repulsion between molecules and the Coulomb attractive interaction of dipoles with the liquid surface. It is shown that the former favors a perpendicular alignment of molecules at the surface (SmA(p) phase) and the latter gives a tilted orientation (SmCp phase). As the temperature decreases, the competition between these two interactions leads to a second-order phase transition from SmA(p) to SmCp. The large pretransitional fluctuation of the tilt angle at a critical molecular area is predicted. (C) 1999 Elsevier Science B.V. All rights reserved.
部门归属Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan; Tsing Hua Univ, Ctr Adv Study, Beijing 100084, Peoples R China; Acad Sinica, Inst Theoret Phys, Beijing 100080, Peoples R China
关键词Maxwell Displacement Current Air Interface Simulation Dynamics Microscopy Films Model
学科领域Physics
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收录类别SCI
WOS记录号WOS:000083203600002
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被引频次:7[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/13085
专题理论物理所1978-2010年知识产出
通讯作者Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
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Iwamoto, M,Wu, CX,Zhong-can, OY,et al. Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface[J]. CHEMICAL PHYSICS LETTERS,1999,312(1):7-13.
APA Iwamoto, M,Wu, CX,Zhong-can, OY,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan..(1999).Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface.CHEMICAL PHYSICS LETTERS,312(1),7-13.
MLA Iwamoto, M,et al."Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface".CHEMICAL PHYSICS LETTERS 312.1(1999):7-13.
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