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Iwamoto, M; Wu, CX; Zhong-can, OY; Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface
Source PublicationCHEMICAL PHYSICS LETTERS
KeywordMaxwell Displacement Current Air Interface Simulation Dynamics Microscopy Films Model
AbstractMonolayers of amphiphilic molecules at the liquid-air interface are investigated, taking into account the steric repulsion between molecules and the Coulomb attractive interaction of dipoles with the liquid surface. It is shown that the former favors a perpendicular alignment of molecules at the surface (SmA(p) phase) and the latter gives a tilted orientation (SmCp phase). As the temperature decreases, the competition between these two interactions leads to a second-order phase transition from SmA(p) to SmCp. The large pretransitional fluctuation of the tilt angle at a critical molecular area is predicted. (C) 1999 Elsevier Science B.V. All rights reserved.
1999
ISSN0009-2614
Volume312Issue:1Pages:7-13
Subject AreaPhysics
Indexed BySCI
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Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.itp.ac.cn/handle/311006/13085
Collection理论物理所科研产出_SCI论文
Corresponding AuthorIwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan.
Recommended Citation
GB/T 7714
Iwamoto, M,Wu, CX,Zhong-can, OY,et al. Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface[J]. CHEMICAL PHYSICS LETTERS,1999,312(1):7-13.
APA Iwamoto, M,Wu, CX,Zhong-can, OY,&Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, 2-12-1 O Okayama, Tokyo 1528552, Japan..(1999).Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface.CHEMICAL PHYSICS LETTERS,312(1),7-13.
MLA Iwamoto, M,et al."Tilting phase transition of Langmuir monolayers: a competition between steric repulsion and interaction of dipolar molecules with liquid surface".CHEMICAL PHYSICS LETTERS 312.1(1999):7-13.
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