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题名: Detection of phase transition of monolayers at the air-water interface by compression using Maxwell displacement current and optical second harmonic generation
作者: Tojima, A ;  Manaka, T ;  Iwamoto, M ;  Zhong-can, OY
刊名: JOURNAL OF CHEMICAL PHYSICS
出版日期: 2003
卷号: 118, 期号:12, 页码:5640-5649
关键词: FATTY-ACID MONOLAYER ;  2ND-HARMONIC GENERATION ;  MOLECULAR-ORIENTATION ;  LANGMUIR MONOLAYERS ;  SPECTROSCOPY ;  FILMS ;  SURFACE ;  SHEAR ;  ORDER
学科分类: Physics
通讯作者: Iwamoto, M , Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, O Okayama 2-12-2, Tokyo 1528552, Japan.
部门归属: Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan; Tsing Hua Univ, Ctr Adv Study, Beijing 10084, Peoples R China; Acad Sinica, Inst Theoret Phys, Beijing 100080, Peoples R China
英文摘要: The spontaneous and nonlinear dielectric polarization of Langmuir monolayers is expressed using orientational order parameters. With the theoretical calculations, the Maxwell displacement current (MDC) measurement coupled with optical second harmonic generation (SHG) measurement is shown to be helpful for the study of orientational orders and phase transitions in monolayers. Spontaneous and nonlinear polarization induced in monolayers are detected by MDC and SHG, respectively. Using the MDC-SHG measurement, monolayers of 4'-n-octyl-4-cyanobiphenyl on the water surface were examined by monolayer compression. The phase transitions such as from planar isotropic phase to polar and tilting orientational alignment phases were clearly revealed. (C) 2003 American Institute of Physics.
收录类别: SCI
原文出处: 查看原文
WOS记录号: WOS:000181442100043
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.itp.ac.cn/handle/311006/13339
Appears in Collections:理论物理所1978-2010年知识产出_期刊论文

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Recommended Citation:
Tojima, A,Manaka, T,Iwamoto, M,et al. Detection of phase transition of monolayers at the air-water interface by compression using Maxwell displacement current and optical second harmonic generation[J]. JOURNAL OF CHEMICAL PHYSICS,2003,118(12):5640-5649.
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