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Zhao, HQ; Shi, R; Wang, YT; Wang, YT (reprint author), Chinese Acad Sci, Inst Theoret Phys, Key Lab Frontiers Theoret Phys, Beijing 100190, Peoples R China.
Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions
发表期刊COMMUNICATIONS IN THEORETICAL PHYSICS
语种英语
关键词Electric-field Electrolyte Cells
摘要Nanoscale spatial heterogeneity in ionic liquids is formed by the aggregation of cationic tail groups. The electrostatic interactions between polar groups and the collective van der Waals interactions between nonpolar tail groups both contribute to the formation of tail domains, but the degrees of their contributions were unknown. In this work, by applying a strong external electric field to effectively overpower the electrostatic interactions between polar groups, we have determined that the tail aggregation is majorly attributed to the electrostatic interactions and the van der Waals interactions only have minor influence on the spatial heterogeneity phenomenon of ionic liquids.
2011
ISSN0253-6102
卷号56期号:3页码:499-503
学科领域Physics
收录类别SCI
项目资助者Chinese Academy of Sciences; National Natural Science Foundation of China [10974208] ; Chinese Academy of Sciences; National Natural Science Foundation of China [10974208] ; Chinese Academy of Sciences; National Natural Science Foundation of China [10974208] ; Chinese Academy of Sciences; National Natural Science Foundation of China [10974208]
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被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/14281
专题理论物理所科研产出_SCI论文
通讯作者Wang, YT (reprint author), Chinese Acad Sci, Inst Theoret Phys, Key Lab Frontiers Theoret Phys, Beijing 100190, Peoples R China.
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GB/T 7714
Zhao, HQ,Shi, R,Wang, YT,et al. Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions[J]. COMMUNICATIONS IN THEORETICAL PHYSICS,2011,56(3):499-503.
APA Zhao, HQ,Shi, R,Wang, YT,&Wang, YT .(2011).Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions.COMMUNICATIONS IN THEORETICAL PHYSICS,56(3),499-503.
MLA Zhao, HQ,et al."Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions".COMMUNICATIONS IN THEORETICAL PHYSICS 56.3(2011):499-503.
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