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题名: Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions
作者: Zhao, HQ ;  Shi, R ;  Wang, YT
刊名: COMMUNICATIONS IN THEORETICAL PHYSICS
出版日期: 2011
卷号: 56, 期号:3, 页码:499-503
关键词: ELECTRIC-FIELD ;  ELECTROLYTE ;  CELLS
学科分类: Physics
通讯作者: Wang, YT (reprint author), Chinese Acad Sci, Inst Theoret Phys, Key Lab Frontiers Theoret Phys, Beijing 100190, Peoples R China.
部门归属: [Zhao Hai-Qing; Shi Rui; Wang Yan-Ting] Chinese Acad Sci, Inst Theoret Phys, Key Lab Frontiers Theoret Phys, Beijing 100190, Peoples R China; [Zhao Hai-Qing] NE Normal Univ, Dept Phys, Changchun 130024, Peoples R China
英文摘要: Nanoscale spatial heterogeneity in ionic liquids is formed by the aggregation of cationic tail groups. The electrostatic interactions between polar groups and the collective van der Waals interactions between nonpolar tail groups both contribute to the formation of tail domains, but the degrees of their contributions were unknown. In this work, by applying a strong external electric field to effectively overpower the electrostatic interactions between polar groups, we have determined that the tail aggregation is majorly attributed to the electrostatic interactions and the van der Waals interactions only have minor influence on the spatial heterogeneity phenomenon of ionic liquids.
资助者: Chinese Academy of Sciences; National Natural Science Foundation of China [10974208]
收录类别: SCI
原文出处: 查看原文
语种: 英语
WOS记录号: WOS:000294995000019
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.itp.ac.cn/handle/311006/14281
Appears in Collections:理论物理所2011年知识产出_期刊论文

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Recommended Citation:
Zhao, HQ,Shi, R,Wang, YT. Nanoscale Tail Aggregation in Ionic Liquids: Roles of Electrostatic and van der Waals Interactions[J]. COMMUNICATIONS IN THEORETICAL PHYSICS,2011,56(3):499-503.
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