ITP OpenIR  > 理论物理所SCI论文
Effect of the Chain Length on the Structure of Ionic Liquids: from Spatial Heterogeneity to Ionic Liquid Crystals
Ji, YM; Shi, R; Wang, YT; Saielli, G; Wang, YT (reprint author), Chinese Acad Sci, Inst Theoret Phys, State Key Lab Theoret Phys, 55 E Zhongguancun Rd,POB 2735, Beijing 100190, Peoples R China.
2013
发表期刊JOURNAL OF PHYSICAL CHEMISTRY B
ISSN1520-6106
卷号117期号:4页码:1104-1109
摘要Ionic liquids with intermediate nonpolar cationic side-chain lengths are known to have nanoscale spatial heterogeneities with nonpolar tail domains separated by a continuous polar network. In this work, we use coarse-grained molecular dynamics simulations to show that, when the nonpolar cationic side chain is sufficiently long, due to the stronger van der Waals interactions between the side chains, the structure of ionic liquids goes through a transition from spatially heterogeneous to liquid crystalline-like. For XMIm(+)/NO3- ionic liquids, change occurs when the number of carbon groups on the cationic side chain varies from 14 to 16. In the liquid crystal-like phase, the cationic side chains tend to be parallel to each other, while the cationic head groups and anions, although being mostly layered perpendicularly to the direction along the side chains, still form a continuous polar network.
部门归属[Ji, Yumeng; Shi, Rui; Wang, Yanting] Chinese Acad Sci, Inst Theoret Phys, State Key Lab Theoret Phys, Beijing 100190, Peoples R China; [Saielli, Giacomo] CNR, Ist Tecnol Membrane, Unita Padova, I-35131 Padua, Italy
关键词Coarse-grained Models Nanostructural Organization Tail Aggregation Solar-cells Dynamics Salts Simulation Behavior Systems
学科领域Physics
资助者National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO
URL查看原文
收录类别SCI
语种英语
资助者National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO ; National Natural Science Foundation of China [10974208, 11121403]; Chinese Academy of Sciences (CAS); CAS-CNR; MIUR [PRIN 20085M27SS, FIRB RBAP11C58Y]; Fondazione CARIPARO
WOS记录号WOS:000314492300015
引用统计
被引频次:72[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/15427
专题理论物理所SCI论文
通讯作者Wang, YT (reprint author), Chinese Acad Sci, Inst Theoret Phys, State Key Lab Theoret Phys, 55 E Zhongguancun Rd,POB 2735, Beijing 100190, Peoples R China.
推荐引用方式
GB/T 7714
Ji, YM,Shi, R,Wang, YT,et al. Effect of the Chain Length on the Structure of Ionic Liquids: from Spatial Heterogeneity to Ionic Liquid Crystals[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2013,117(4):1104-1109.
APA Ji, YM,Shi, R,Wang, YT,Saielli, G,&Wang, YT .(2013).Effect of the Chain Length on the Structure of Ionic Liquids: from Spatial Heterogeneity to Ionic Liquid Crystals.JOURNAL OF PHYSICAL CHEMISTRY B,117(4),1104-1109.
MLA Ji, YM,et al."Effect of the Chain Length on the Structure of Ionic Liquids: from Spatial Heterogeneity to Ionic Liquid Crystals".JOURNAL OF PHYSICAL CHEMISTRY B 117.4(2013):1104-1109.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Effect of the Chain (5095KB) 开放获取使用许可请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Ji, YM]的文章
[Shi, R]的文章
[Wang, YT]的文章
百度学术
百度学术中相似的文章
[Ji, YM]的文章
[Shi, R]的文章
[Wang, YT]的文章
必应学术
必应学术中相似的文章
[Ji, YM]的文章
[Shi, R]的文章
[Wang, YT]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。