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Man, XK; Tang, JZ; Zhou, P; Yan, DD; Andelman, D; Man, XK (reprint author), Beihang Univ, Ctr Soft Matter Phys & Its Applicat, Beijing 100191, Peoples R China.
Lamellar Diblock Copolymers on Rough Substrates: Self-Consistent Field Theory Studies
发表期刊MACROMOLECULES
语种英语
摘要We present numerical calculations of lamellar phases of diblock copolymers (BC?) confined between two surfaces, where the top surface is flat and the bottom one is corrugated. The corrugated substrate is assumed to have a single q-mode of lateral undulations with a wavenumber q(s) and amplitude R. We focus on the effects of substrate roughness, parametrized by the dimensionless quantity, q(s)R, on the relative stability between parallel and perpendicular orientations of the lamellar phase. The competition between film confinement, energy cost of elastic deformation, and gain in surface energy induces a parallel-to-perpendicular transition of the BC? lamellae. Employing self-consistent field theory (SCFT), we study the critical value, (q(s)R)*, corresponding to this transition. The (q(s)R)* value increases as a function of the surface preference toward one of the two BCP components and as a function of film thickness. But, (q(s)R)* decreases with increasing values of the Flory-Huggins parameter, N chi(AB). Our findings are equivalent to stating that the critical (q(s)R)* value decreases as the BCP molecular weight or the natural BCP periodicity increases. We further show that the rough substrate can overcome the formation of parallel lamellae in cases where the top surface has a preference toward one of the two BC? components. Our results are in good agreement with previous experiments and highlight the physical conditions behind the perpendicular orientation of lamellar phases, as is desired in nanolithography and other industrial applications.
2015
卷号48期号:20页码:7689-7697
学科领域Polymer Science
DOIhttp://dx.doi.org/10.1021/acs.macromol.5b01362
收录类别SCI
项目资助者National Natural Science Foundation of China (NSFC) [21404003, 21434001, 21374011] ; National Natural Science Foundation of China (NSFC) [21404003, 21434001, 21374011] ; National Natural Science Foundation of China (NSFC) [21404003, 21434001, 21374011] ; National Natural Science Foundation of China (NSFC) [21404003, 21434001, 21374011] ; Ministry of Science and Technology (MOST) [2011CB808502] ; Ministry of Science and Technology (MOST) [2011CB808502] ; Ministry of Science and Technology (MOST) [2011CB808502] ; Ministry of Science and Technology (MOST) [2011CB808502] ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Israel Science Foundation (ISF) [438/12] ; Israel Science Foundation (ISF) [438/12] ; Israel Science Foundation (ISF) [438/12] ; Israel Science Foundation (ISF) [438/12] ; United States-Israel Binational Science Foundation (BSF) [2012/060] ; United States-Israel Binational Science Foundation (BSF) [2012/060] ; United States-Israel Binational Science Foundation (BSF) [2012/060] ; United States-Israel Binational Science Foundation (BSF) [2012/060]
引用统计
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/20812
专题理论物理所科研产出_SCI论文
通讯作者Man, XK (reprint author), Beihang Univ, Ctr Soft Matter Phys & Its Applicat, Beijing 100191, Peoples R China.
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GB/T 7714
Man, XK,Tang, JZ,Zhou, P,et al. Lamellar Diblock Copolymers on Rough Substrates: Self-Consistent Field Theory Studies[J]. MACROMOLECULES,2015,48(20):7689-7697.
APA Man, XK,Tang, JZ,Zhou, P,Yan, DD,Andelman, D,&Man, XK .(2015).Lamellar Diblock Copolymers on Rough Substrates: Self-Consistent Field Theory Studies.MACROMOLECULES,48(20),7689-7697.
MLA Man, XK,et al."Lamellar Diblock Copolymers on Rough Substrates: Self-Consistent Field Theory Studies".MACROMOLECULES 48.20(2015):7689-7697.
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