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The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture
Shen, YW; Ou-Yang, ZC; Hao, JC; Lin, HT; Jiang, LH; Liu, ZH; Gao, XH; Gao, XH (reprint author), Shandong Acad Agr Sci, Inst Agr Resources & Environm, Jinan 250100, Peoples R China.
2016
发表期刊COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷号500页码:40-44
文章类型Article
摘要A mixture of cationic and anionic fluorinated surfactants can form faceted vesicles and punctured lamellar phase when there is excess surface charge, in which both cationic and anionic fluorinated surfactants are stiff in the membrane as phospholipids in the frozen "crystalline" or "gel" phase. Here, a model was established to demonstrate the mechanism of the formation and transition of the aggregates with different morphologies. With excess cationic surface charge, the gel-like faceted vesicles and punctured lamellae can transform into smooth-shaped vesicles at high temperature. The freeze-fracture transmission electron microscope (FF-TEM) and X-ray diffraction (XRD) were used to identify the segregation and phase sequence of semi-fluorinated cationic and anionic surfactant membranes with different excess surface charge. (C) 2016 Elsevier B.V. All rights reserved.
关键词Cat-anionic Fluorinated Surfactant Faceted Vesicle Punctured Lamellae Surface Charge Self-assembly
学科领域Chemistry
资助者Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position ; Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position
DOIhttp://dx.doi.org/10.1016/j.colsurfa.2016.03.063
关键词[WOS]LIQUID-CRYSTALS ; AGGREGATION BEHAVIOR ; PHASE-BEHAVIOR ; SYSTEMS ; WATER ; MEMBRANES ; EXCESS
收录类别SCI
语种英语
资助者Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position ; Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Young Talents Training Program of Shandong Academy of Agricultural Sciences ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Shandong Provincial Key Laboratory of Plant Nutrition and Fertilizer ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position ; Special Fund for "Taishan Scholar" construction engineering "agricultural nonpoint source pollution prevention and control" position
WOS类目Chemistry, Physical
引用统计
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/21598
专题2016年知识产出
通讯作者Liu, ZH; Gao, XH (reprint author), Shandong Acad Agr Sci, Inst Agr Resources & Environm, Jinan 250100, Peoples R China.
推荐引用方式
GB/T 7714
Shen, YW,Ou-Yang, ZC,Hao, JC,et al. The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2016,500:40-44.
APA Shen, YW.,Ou-Yang, ZC.,Hao, JC.,Lin, HT.,Jiang, LH.,...&Gao, XH .(2016).The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,500,40-44.
MLA Shen, YW,et al."The mechanism for the transition from vesicles to punctured lamellae and faceted vesicles in cationic and anionic fluorinated surfactant mixture".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 500(2016):40-44.
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