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Li, Shen1; Wang, Yanting1![]() | |
Percolation Phase Transition from Ionic Liquids to Ionic Liquid Crystals | |
Source Publication | SCIENTIFIC REPORTS
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Language | 英语 |
Keyword | NANOSTRUCTURAL ORGANIZATION SPATIAL HETEROGENEITY DYNAMICS |
Abstract | Due to their complex molecular structures and interactions, phase behaviors of complex fluids are quite often difficult to be identified by common phase transition analysis methods. Percolation phase transition, on the other hand, only monitors the degree of connection among particles without strict geometric requirements such as translational or orientational order, and thus suitable for pinpointing phase transitions of complex fluids. As typical complex fluids, ionic liquids (ILs) exhibit phases beyond the description of simple liquid theories. In particular, with an intermediate cationic side-chain length, ILs can form the nanoscale segregated liquid (NSL) state, which will eventually transform into the ionic liquid crystal (ILC) structure when the side chains are adequately long. However, the microscopic mechanism of this transformation is still unclear. In this work, by means of coarse-grained molecular dynamics simulation, we show that, with increasing cationic side-chain length, some local pieces of non-polar domains are gradually formed by side chains aligned in parallel inside the NSL phase, before an abrupt percolation phase transition happens when the system transforms into the ILC phase. This work not only identifies that the NSL to ILC phase transition is a critical phenomenon, but also demonstrates the importance of percolation theory to complex fluids. |
2019 | |
ISSN | 2045-2322 |
Volume | 9Pages:13169 |
Cooperation Status | 国内 |
Subject Area | Science & Technology - Other Topics |
MOST Discipline Catalogue | Multidisciplinary Sciences |
DOI | 10.1038/s41598-019-49493-3 |
Indexed By | SCIE |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.itp.ac.cn/handle/311006/27052 |
Collection | SCI期刊论文 计算平台成果 |
Affiliation | 1.Chinese Acad Sci, Inst Theoret Phys, CAS Key Lab Theoret Phys, 55 East Zhongguancun Rd,POB 2735, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Phys Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
Recommended Citation GB/T 7714 | Li, Shen,Wang, Yanting. Percolation Phase Transition from Ionic Liquids to Ionic Liquid Crystals[J]. SCIENTIFIC REPORTS,2019,9:13169. |
APA | Li, Shen,&Wang, Yanting.(2019).Percolation Phase Transition from Ionic Liquids to Ionic Liquid Crystals.SCIENTIFIC REPORTS,9,13169. |
MLA | Li, Shen,et al."Percolation Phase Transition from Ionic Liquids to Ionic Liquid Crystals".SCIENTIFIC REPORTS 9(2019):13169. |
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File Name/Size | DocType | Version | Access | License | ||
Percolation Phase Tr(4315KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | Application Full Text |
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