ITP OpenIR  > 1978-2010年知识产出
Surface freezing in normal alkanes: A statistical physics approach
Zhang, Y; Ou-Yang, ZC; Iwamoto, M; Zhang, Y , Chinese Acad Sci, Interdisciplinary Ctr Theoret Studies, POB 2735, Beijing 100080, Peoples R China
2006
发表期刊JOURNAL OF CHEMICAL PHYSICS
ISSN0021-9606
卷号124期号:21页码:-
摘要The present paper aims to understand the surface freezing occurring on the interface between liquid normal alkane and air. After proposing a simple microscopic model, it reveals that the model can describe the surface freezing of normal alkanes. Subsequently, surface freezing is immediately proved to be a first order phase transition, which has been illustrated by numerous experiments. Moreover, our calculation predicts a new first. order phase transition on the interface. These two transitions correspond to the liquid to monolayer and monolayer to perfect solid transitions, respectively. A phase diagram is obtained directly from the calculations as well. The model indicates that both van der Waals interaction and the entropy influenced by the surface are essential for explaining the surface phase transition. (c) 2006 American Institute of Physics.
部门归属Chinese Acad Sci, Interdisciplinary Ctr Theoret Studies, Beijing 100080, Peoples R China; Chinese Acad Sci, Inst Theoret Phys, Beijing 100080, Peoples R China; Tsing Hua Univ, Ctr Adv Study, Beijing 100084, Peoples R China; Tokyo Inst Technol, Dept Phys Elect, Meguro Ku, Tokyo 1528552, Japan
关键词Phase-transition Chain Molecules Macromolecules Interfaces Layers
学科领域Physics
URL查看原文
收录类别SCI
WOS记录号WOS:000238758700050
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.itp.ac.cn/handle/311006/5967
专题1978-2010年知识产出
通讯作者Zhang, Y , Chinese Acad Sci, Interdisciplinary Ctr Theoret Studies, POB 2735, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Y,Ou-Yang, ZC,Iwamoto, M,et al. Surface freezing in normal alkanes: A statistical physics approach[J]. JOURNAL OF CHEMICAL PHYSICS,2006,124(21):-.
APA Zhang, Y,Ou-Yang, ZC,Iwamoto, M,&Zhang, Y , Chinese Acad Sci, Interdisciplinary Ctr Theoret Studies, POB 2735, Beijing 100080, Peoples R China.(2006).Surface freezing in normal alkanes: A statistical physics approach.JOURNAL OF CHEMICAL PHYSICS,124(21),-.
MLA Zhang, Y,et al."Surface freezing in normal alkanes: A statistical physics approach".JOURNAL OF CHEMICAL PHYSICS 124.21(2006):-.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
Surface freezing in (695KB) 开放获取使用许可请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang, Y]的文章
[Ou-Yang, ZC]的文章
[Iwamoto, M]的文章
百度学术
百度学术中相似的文章
[Zhang, Y]的文章
[Ou-Yang, ZC]的文章
[Iwamoto, M]的文章
必应学术
必应学术中相似的文章
[Zhang, Y]的文章
[Ou-Yang, ZC]的文章
[Iwamoto, M]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。